Principle of operationThe measuring principle is based on the different thermal conductivity of gases. The CALOMAT 6 works with a micromechanically produced Si chip whose measuring membrane is equipped with thin-film resistors. The resistors are kept at a constant temperature. This requires an current intensity depending on the thermal conductivity of the sample gas. This "raw value" is processed further electronically to calculate the gas concentration. The sensor is located in a thermostatically-controlled stainless steel enclosure in order to prevent the influence of changes in ambient temperature. To prevent the influence of changes in flow, the sensor is positioned in a bore located to the side of the main flow. Note The sample gases must be fed into the analyzers free of dust. Condensation (dew point sample gas < ambient temperature) is to be avoided in the measurement chambers. Therefore, the use of gas modified for the measuring tasks is necessary in most application cases. CALOMAT, principle of operation Essential characteristics
Measuring spansThe smallest and largest possible spans depend on both the measured component (type of gas) and the respective application. The smallest possible spans listed below refer to N2 as the residual gas. With other gases which have a larger/smaller thermal conductivity than N2, the smallest possible span is also larger/smaller.
Influence of interfering gasesKnowledge of the sample gas composition is necessary to determine the influence of residual gases with several interfering components. The following table lists the zero offsets expressed in % H2 resulting from 10 % residual gas (interfering gas) in each case.
For residual gas concentrations differing from 10 %, the corresponding multiple of the associated value in the table provides an acceptable approximation. This is valid for for residual gas concentrations up to 25 % (dependent on type of gas). The thermal conductivity of most gas mixtures has a non-linear response. Even ambiguous results, such as e.g. with NH3/N2 mixtures, can occur within a specific concentration range. In addition to a zero offset, it should also be noted that the gradient of the characteristic is influenced by the residual gas. However, this effect is negligible for most gases. In case of correction of the influence of interfering gases with additional analyzers (ULTRAMAT 6/ULTRAMAT 23), the resulting measuring error can – depending on the application – amount up to 5 % of the smallest measuring range of the respective application. Example of correction of cross-interferenceSpecification for the interface cable
Bus terminating resistorsPins 3-7 and 8-9 of the first and last connectors of a bus cable must be bridged (see graphic). Note It is advisable to install a repeater on the device side in the case of a cable length of more than 500 m or with high interferences. Up to four components can be corrected via the ELAN bus, correction of cross-interference can be carried out for one or two components via the analog input. Bus cable with plug connections, example |
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