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Live injection
The SITRANS CV has a two-stage injection system. Using a micro injection valve, a defined quantity of sample is first brought up to the carrier gas pressure. This eliminates the pressure-dependent error in the dosing quantity present with conventional systems. In the second stage, the sample is transferred to the column by a valveless micro injection system (live dosing). The result is an "active" injection.
The injection volume can be varied time-controlled, and exactly matched to the column requirements.
Valveless live column switching
Because of the high dead volume of conventional valves, only the valveless version can be considered for a miniaturized system. In this case, the generation of differences in flow using several electronic pressure regulators at appropriate positions of the column setup causes a change in the flow directions. (The system operates according to the Wheatstone principle, but pneumatically.) The functions "Cut" and "Backflushing" can then be implemented free of dead volume.
The column system
The column system consists of three capillary columns connected in sequence. Micro TCDs or micro live circuits are installed in sequence ("inline") upstream and downstream of the individual columns. Three electronic pressure regulators supply the columns with carrier gas and carry out the switching functions (injection, backflushing and cut).
By using narrow-bore capillary columns, the separation at high resolution is carried out within a much shorter time, approx. factor 2 to 3 compared to standard capillary columns.
Electronic pressure regulators
A high pressure stability together with rapid changing rates in the hPa range are required for precise and fast switching. This is achieved in the electronic pressure regulators by means of a piezo actuator.
Detector
The micro TCDs (silicon wafer technology) work on the principle of continuous measurement of the different thermal conductivities of the carrier gas and the components to be measured.
The measurement can be carried out without falsification by avoiding catalytic effects on the heating wires and maintaining a constant flow velocity. This permits consistent in-line detection, i.e. without qualitative or quantitative losses of substances.
Modules
The standardized application modules generally feature live injection and live switching functions, detectors and three separating columns.
|
Detector |
Column 1 |
Detector |
Column 2 |
Detector |
Circuit |
Column 3 |
Detector |
|
|---|---|---|---|---|---|---|---|---|
|
C09 Injection |
Sil5 Non-polar aromatic and aliphatic hydrocarbons |
TCD |
Sil5 Non-polar aromatic and aliphatic hydrocarbons |
TCD |
Live |
Porabond Q All components except molecular filter components |
TCD |
|
|
C01 Injection |
TCD |
Sil5 C3, C4, C5, C6+ |
TCD |
PoraPLOT/Porabond Q CO2, C2, H2O |
TCD |
Live |
Molecular filter H2, (Ar+O2), N2, C1, CO |
TCD |
Application
The SITRANS CV is a storage product. Precalibration is carried out at the factory, using helium and argon (as the carrier gas) and a calibration gas. The measured components and switching functions (live injection, backflushing, cut) are saved in the GC. The calibration process itself should be performed during commissioning on-site.
Measurements can be made within the following working ranges:
|
Component |
Checked working range (%) |
Possible working range (%) |
|---|---|---|
|
Methane |
57 ... 100 |
50 ... 100 |
|
Nitrogen1) |
0 ... 22 |
0 ... 25 |
|
Carbon dioxide |
0 ... 12 |
0 ... 20 |
|
Ethane |
0 ... 14 |
0 ... 20 |
|
Propane |
0 ... 5 |
0 ... 15 |
|
i-butane |
0 ... 0.9 |
0 ... 10 |
|
n-butane |
0 ... 1.8 |
0 ... 10 |
|
Neopentane |
0 ... 0.1 |
0 ... 1 |
|
i-pentane |
0 ... 0.12 |
0 ... 1 |
|
n-pentane |
0 ... 0.12 |
0 ... 1 |
|
Hexane+2) |
0 ... 0.08 |
0 ... 3 |
|
Hexane |
0 ... 1 |
|
|
Heptane+3) |
0 ... 1 |
|
|
Octane |
0 ... 1 |
|
|
Nonane+4) |
0 ... 1 |
|
|
Helium |
Concentration can be entered as a fixed value in the components list |
|
|
H2S
|
< 500 ppm |
No measured component |
Measured components and performance parameters for Pos. 8_0 (master setup, standard calorific value analysis in accordance with ISO 6976-1995)
1) Any oxygen or carbon monoxide present in the sample will be detected along with the nitrogen and, therefore, taken into account when the nitrogen concentration is determined.
2) Hexane+ = group(iso/n-hexane to iso/n-nonane)
3) Heptane+ = group(iso/n-hexane) and group(iso/n-heptane to iso/n-nonane)
4) Nonane+ = group(iso/n-hexane), group(iso/n-heptane), group(iso/n-octane), group(iso/n-nonane)
|
Component |
Possible working range (%) |
|---|---|
|
Oxygen |
0 ... 4 |
Measuring range of the additional measured component oxygen of the extended calorific value analysis (see Order No. 7KQ3105-1)
The remark in footnote 1 about the detection of oxygen and nitrogen is not valid in the case of an extended calorific value analysis. In this case, all components from the Table "Measured components and performance parameters for Pos. 8_0 (master setup, standard calorific value analysis in accordance with ISO 6976-1995)" plus oxygen are detected and quantified.
Analyses within the checked working range as well as the quality parameters resulting from these (upper and lower calorific values, density, relative density and Wobbe index) correspond to the requirements listed below.
Measurements within the scope of the possible working ranges (Table "Measured components and performance parameters for Pos. 8_0 (Master setup, standard analysis of calorific value in accordance with ISO 6976-1995)", right column, and Table "Measuring range of the additional measured component oxygen of the extended analysis of calorific value (see Order No. 7KQ3105-1)") are possible. However, checking of the repeatability and correctness has not been carried out by the official German body "Physikalisch technischer Bundesanstalt (PTB)".
|
Concentration range (mol.%) |
Repeatability according to ISO 6974-5 (2001); molar fraction (%), absolute |
|---|---|
|
50 < xi < 100 |
0.1 |
|
1 < xi < 50 |
0.011 |
|
0.1 < xi < 1 |
0.006 |
|
xi < 0.1 |
The repeatability of the measured components complies with ISO 6974-5 (2001) – Annex B
The repeatability of the calorific value and standard density achieve a relative standard deviation of < 0.015%.
The calibration gas is an extremely important factor for consideration in terms of the MPE (maximum permissible error), and has a significant effect on the accuracy of the overall measuring system. For this reason, SITRANS CV - based on a comparative measuring procedure - can never be more accurate than the calibration gas used. Other parameters besides the accuracy data on the calibration gas certificate are important for the accuracy of a system. Examples of these include the optimum gas composition, the ambient temperatures of the calibration gas cylinders during transportation and operation, potential condensation of, for instance, higher hydrocarbons in a calibration gas cylinder, and the functionality of the sample preparation system.
Under optimum conditions, the SITRANS CV achieves an MPE of < 0,1 % for the calorific value and standard density.
SITRANS CV is designed for measuring different types of natural gas. The table below lists the typical specifications of natural gases (measured and residual components):
|
Dutch natural gas |
Russian natural gas |
Algerian natural gas |
LNG |
|
|---|---|---|---|---|
|
Helium |
0.035 |
0.007 |
0.150 |
0.045 |
|
Nitrogen |
2.072 |
0.873 |
5.493 |
0.948 |
|
CO2 |
1.131 |
0.102 |
0.210 |
0.000 |
|
Hydrogen |
0.000 |
0.000 |
0.000 |
0.000 |
|
CO |
0.000 |
0.000 |
0.000 |
0.000 |
|
Methane |
90.179 |
98.022 |
83.774 |
89.373 |
|
Ethane |
4.976 |
0.701 |
7.660 |
7.793 |
|
Propane |
1.161 |
0.204 |
1.892 |
1.421 |
|
i-butane |
0.144 |
0.035 |
0.256 |
0.178 |
|
n-butane |
0.186 |
0.035 |
0.345 |
0.238 |
|
Neopentane |
0.005 |
0.0005 |
||
|
i-pentane |
0.038 |
0.007 |
0.070 |
0.001 |
|
n-pentane |
0.031 |
0.005 |
0.079 |
0.001 |
|
Hexane+ |
0.047 |
0.009 |
0.071 |
0.002 |
|
O2+Ar |
0.000 |
0.000 |
0.000 |
0.000 |
|
H2S |
< 10 mg/m3 |
< 50 mg/m3 |
< 10 mg/m3 |
< 10 mg/m3 |
|
Mercaptan sulfur |
< 20 mg/m3 |
< 20 mg/m3 |
< 20 mg/m3 |
< 20 mg/m3 |
|
H2O |
Dew point < ground temp. for line pressure in each case |
Dew point < ground temp. for line pressure in each case |
Dew point < ground temp. for line pressure in each case |
Dew point < ground temp. for line pressure in each case |
|
Total |
100.000 |
100.000 |
100.000 |
100.000 |
|
Calorific value (KJ/m3) |
39 061,265 |
37 811,062 |
39 604,232 |
4 0797,089 |
|
Heating value (KJ/m3) |
35 250,449 |
34 055,754 |
35 789,664 |
36 842,640 |
|
Density (kg/m3) |
0.75617 |
0.69388 |
0.79422 |
0.75555 |
|
Z factor |
0.99764 |
0.99796 |
0.99752 |
0.99750 |
Composition of Dutch, Russian and Algerian natural gas, as well as LNG
SITRANS CV with SIMATIC Extension Unit